Commutator Matrix in Phase Space Mapping Models for Nonadiabatic Quantum Dynamics
نویسندگان
چکیده
We show that a novel, general phase space mapping Hamiltonian for nonadiabatic systems, which is reminiscent of the renowned Meyer–Miller Hamiltonian, involves commutator variable matrix rather than conventional zero-point-energy parameter. In exact formulation on constraint approaches dynamics, with variables can be employed to generate approximate trajectory-based dynamics. Various benchmark model tests, range from gas condensed suggest overall performance better Hamiltonian.
منابع مشابه
Nonadiabatic Geometric Phase in Quaternionic Hilbert Space
We develop the theory of the nonadiabatic geometric phase, in both the Abelian and non-Abelian cases, in quaternionic Hilbert space.
متن کاملQuantum phase space distributions in thermofield dynamics
It is shown that the the quantum phase space distributions corresponding to a density operator ρ can be expressed, in thermofield dynamics, as overlaps between the state | ρ > and ”thermal” coherent states. The usefulness of this approach is brought out in the context of a master equation describing a nonlinear oscillator for which exact expressions for the quantum phase distributions for an ar...
متن کاملOn matrix elements of phase-angular momentum commutator in Hilbert space of arbitrary dimensions
We discuss correspondence between the predictions of quantum theories for rotation angle formulated in infinite and finite dimensional Hilbert spaces, taking as example, the calculation of matrix elements of phaseangular momentum commutator. A new derivation of the matrix elements is presented in infinite space, making use of a unitary transformation that maps from the state space of periodic f...
متن کاملPhase space dynamics of overdamped quantum systems
The phase space dynamics of dissipative quantum systems in strongly condensed phase is considered. Based on the exact path integral approach it is shown that the Wigner transform of the reduced density matrix obeys a time evolution equation of Fokker-Planck type valid from high down to very low temperatures. The effect of quantum fluctuations is discussed and the accuracy of these findings is t...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Physical Chemistry A
سال: 2021
ISSN: ['1089-5639', '1520-5215']
DOI: https://doi.org/10.1021/acs.jpca.1c04429